Abstract

The escalating global accumulation of plastic waste (PW) poses a critical obstacle to environmental sustainability, necessitating the development of viable valorization strategies. Pyrolysis process offers a thermo-chemical conversion pathway capable of transforming waste plastics into a potentially functional liquid product. This work presents a systematic and comprehensive investigation of the physicochemical, wettability, thermal stability, rheological, and tribological properties of pyrolysis oil (i.e., pyro-oil) derived from virgin linear low-density polyethylene (LLDPE) pellets to mimic the behavior of common polymers in such thermo-chemical conversion processes. Pyro-oil was produced under controlled slow pyrolysis conditions in a fixed-bed reactor at 700 °C, and its properties were benchmarked against tire-derived pyro-oil and a commercial engine oil. Chemical and structural characterization was conducted via Fourier transform infrared spectroscopy (FTIR), wavelength dispersive X-ray fluorescence (WDXRF), and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). Wettability was evaluated through temperature-dependent contact angle measurements, and thermal stability was assessed by thermogravimetric analysis (TGA). Rheological profiling of the plastic pyro-oil was investigated using a rheometer apparatus at different temperatures. Lastly, the tribological properties of plastic pyro-oils at various temperatures were examined using a tribometer instrument in a ball-on-disk configuration. Results demonstrate that plastic-derived pyro-oil exhibits a hydrocarbon-dominant chemical composition similar to that of tire pyro-oil and engine oil. Its absolute viscosity is nearly similar to that of the tire pyro-oil and is lower than that of engine oil across different temperatures. Tribological testing revealed that the plastic pyro-oil results in lower friction at elevated temperatures compared to both tire pyro-oil and commercial engine oil. However, the thermal examinations showed that plastic pyro-oil has lower thermal stability than tire pyro-oil and engine oil. Overall, these findings indicate that plastic pyro-oil holds promise as a functional lubricant for low-load and moderate-temperature industrial applications, positioning PW pyrolysis as a viable contributor to circular economy strategies in the lubricants sector.

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