Abstract

Direct cyanide leaching of high-carbon gold ores typically results in poor gold extraction due to the “preg-robbing” effect of carbonaceous matter. This study investigates a refractory high-carbon gold ore from Laos. Based on detailed process mineralogy that identified the occurrence state of gold and the distribution of harmful impurities, a combined process consisting of flotation pre-concentration, oxidative roasting, and a Mill–Leach Coordination (MCL) process was developed. The MCL process, which integrates simultaneous grinding and leaching, continuously renews the particle surface and eliminates product-layer diffusion resistance, thereby significantly enhancing gold dissolution efficiency. Kinetic studies demonstrate that the leaching reaction follows the Avrami model and is controlled by internal diffusion, with a derived semi-empirical kinetic equation. This research provides a novel and efficient technical route for treating high-carbon gold ores and offers theoretical guidance for industrial scale-up.

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