Abstract

Gallium oxide is an ultra-wide bandgap semiconductor with excellent opto-electronic properties, making it a highly promising material for a wide range of applications and devices. In this article, we report how the optical, morphological, structural, and compositional properties of β-Ga2O3 thin films deposited by RF Sputtering on silicon substrates are affected by thermal treatments. Ellipsometric spectra recorded at multiple angles of incidence from several samples subjected to thermal annealing in the range of 550–1000 °C were analyzed to extract the optical functions using appropriate multilayer models. This analysis is complemented by compositional, structural, and morphological characterization techniques. We observed two main stages of crystallization with increasing annealing temperature; up to 700 °C, there is an increase in density and then, for 700–1000 °C, there is an improvement in crystallinity. While the refractive index increases continuously throughout this process, we found that the polarizability of the samples decreases in the first stage and increases in the second. These observations demonstrate that thermal treatments are a powerful tool to tune the optical properties of Ga2O3 thin films for device applications.

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