Abstract

Developing sustainable and scalable personal thermal management textiles that simultaneously provide radiative cooling, moisture comfort, and responsible end-of-life management remains challenging. Here, we report a sustainable, scalable, and recyclable bamboo dissolving pulp-derived cellulose/SiO2 fiber (CSF), fabricated by a wet-spinning process involving the dissolution and regeneration of cellulose and nano-SiO2. The resultant CSF exhibits a hierarchical interface-pore structure, which enhances solar scattering (up to 94.56% in 0.4–1.0 μm) by Mie scattering of nano-SiO2 particles and multiple scattering at micro- and nanopore-induced air/cellulose/SiO2 interfaces. By coupling high mid-infrared emissivity of 94.8% (8–13 μm), the CSF demonstrates average daytime sub-ambient cooling of 9.5 °C under hot and humid summer conditions. More importantly, the CSF presents a multiscale water-transport network that integrates molecular water capture (–OH groups), capillary infiltration (nanoscale interfaces between nano-SiO2 and cellulose), and liquid spreading and evaporation (interconnected microchannels between fibers), which realizes larger liquid diffusion area and water-vapor transmission rate (7.55 cm2 and 175.48 g m−2 24 h−1), compared to commercial cotton and polyester. In addition, the CSF demonstrates desirable soil-biodegradation capability, while the feasibility of closed-loop reuse is demonstrated through a single recycling cycle, supporting environmentally friendly wearable cooling textiles. The wet-spinning strategy paves the way for the construction of sustainable, scalable and recyclable fiber for thermal- and moisture-comfort textiles.

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