Abstract

Cu–Fe alloys combine the high electrical conductivity of Cu with the strengthening and magnetic contributions of Fe, making them promising high-strength, electrically conductive functional materials. However, for high-Fe Cu–Fe alloys with Fe contents exceeding 10 wt.%, the microstructural response, texture evolution, and two-phase deformation partitioning during warm rolling remain insufficiently understood. In this study, Cu–10Fe, Cu–15Fe, and Cu–20Fe alloys were investigated to clarify the effect of Fe content on microstructure evolution, texture characteristics, deformation behavior, and property balance after single-pass warm rolling at 500 °C with a 50% reduction. The results show that, as the Fe content increased from 10% to 20%, the Fe-rich phase became progressively denser after warm rolling and gradually transformed from discrete spherical/spindle-like particles into fibrous structures distributed along the rolling direction, while the average grain size of the alloy decreased. EBSD analysis indicates that increasing Fe content weakened the preferred orientation of the Cu matrix. The maximum texture intensity of the Cu matrix decreased from 5.08 to 4.21, and texture showed a weakening trend. The mechanical properties show that, with increasing Fe content, the ultimate tensile strength increased from 434 MPa to 514 MPa, whereas the elongation decreased from 10.7% to 5.1%. This indicates that the increased amount of Fe-rich phase enhanced strength but reduced plasticity; nevertheless, dynamic recovery and local recrystallization induced by warm rolling helped maintain a certain degree of ductility. The electrical conductivity decreased from 19.43% IACS to 16.71% IACS with increasing Fe content, corresponding to a decrease of only approximately 2.7% IACS, suggesting that warm rolling partially mitigated the negative effect of increasing Fe content on electrical conductivity. Based on the combined microstructural, texture, and KAM/GND analyses, the deformation behavior of the alloys with increasing Fe content exhibited a transition from heterogeneous deformation dominated by the Cu matrix/interface to cooperative deformation involving the Fe-rich phase.

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