Abstract

A novel Dy3+-doped self-activated Sr2NaMg2V3O12 (SNMVO) phosphor was synthesized via a high-temperature solid-state reaction method. Its microstructure, surface morphology, valence state, and luminescence properties were investigated. The results showed that the prepared phosphor exhibited bright green emission at 521 nm and yellow emission at 575 nm under 345 nm excitation. The luminescence intensity showed a strong concentration dependence, with an optimal Dy3+ ion doping concentration of 0.05 mol, and the concentration quenching (CQ) mechanism was dipole–dipole (d-d) interaction. Energy transfer between vanadate and Dy3+ was observed, with a maximum transfer efficiency of 63.5%. The thermal activation energy (0.1859 eV) indicated good thermal stability. Furthermore, this phosphor can be used as a yellow phosphor for white light-emitting diodes (wLEDs) and for anti-counterfeiting patterns.

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